Elite CRU - Chemical Resistant Urethane (A & B)

Item Numbers: 8142-0339, 8142-0341, 8142-0344, 8142-0345, 8142-0346, 8142-0347, 8142-0351, 8142-0352, 8142-0354, 8142-0356, 8142-0360

Part A

U.S. Department Of Labor

Occupational Safety And Health Administration

MATERIEL SAFETY DATA SHEET

Required Under USDL Safety And Health Regulations

(29 CFP 1910.1200 "Hazards Communication Standard")

Section I

Manufactured For: Gabriel First Corp.

Emergency Telephone: 1-800-424-9300

Address: 233 W Commercial Street East Rochester, NY 14445

Trade Name & Synonyms: ELITE CRU (PART A)

Chemical Family: Saturated polyester resin solution

Prepared On: 04/30/2005

HIMS Codes:

HEALTH FLAMMABILITY REACITIVITY MPP

2 3 0 G

Section II - Product And Component Data

Component(s) Chemical Name CAS PEL TLV STEL mmHg@temp

*Normal Butyl Acetate 123-86-4 150 ppm 150 ppm 200 ppm 10.0 @ 66 F

Saturated Polyester Polyol Unknown None None None N/A (non hazardous)

Propylene Glycol Monomethyl - 108-65-6 None None None 3.7 @ 68 F

Ether Acetate

*Xylene 1330-20-7 100 ppm 100 ppm 150 ppm 5.1 @ 61 F

Cellulose Acetate Butyrate Ester 9004-36-8 None None None N/A

Methyl N Amyl Ketone 110-43-0 100 ppm 50 ppm None 2.1 @ 68 F

Dibutyltin Dilurate 77-58-7 .1mg/m3 .1mg/m3 .1mg/m3 N/A

Proprietary Non Hazardous Additives Unknown None None None N/A

2,6 Dimethyl - 4, Heptanone 108-83-8 25 ppm 25 ppm None 1.0 @ 90 F

*Ethyl Benzene 100-41-4 100 ppm 100 ppm 125 ppm 1.0 @ 14 F

* Indicates toxic chemical(s) subject to the reporting requirements of Section 313 of Title III and of 40 CFR 372.

Normal Butyl Acetate: Weight Percent; 7

Xylene: Weight Percent; 2

Ethyl Benzene: Weight Percent; < 0.5%

Section III - Physical Data

Boiling Point: 279 - 300 F

Specific Gravity (H₂O=1): 1.0

Vapor Pressure: N/A

Percent, Volatile By Volume(%):

Vapor Density(Air=1):N/A

Evaporation Rate: N/A

Solubility In Water: Negligible

Appearance And Odor: Clear low viscosity liquid with Keytone odor.

Section IV - Fire And Explosion Hazard Data

Flash Point/Method used: 100 F

Flammable Limits: N/A

Extinguishing Media: Foam, Alcohol Foam, CO2, Dry Chemical, Water Fog

Special Fire Fighting Procedures: Do not enter confined fire area without full bunker gear including a positive pressure NIOSH approved self-contained breathing apparatus. Cool all fire exposed containers with water. Minimize contact with material.

Unusual Fire and Explosion Hazards: Closed containers may explode when exposed to extreme heat. Solvent vapors may be heavier than air. Under conditions of stagnant air, vapors may build up and travel along the ground to an ignition source of the vapors. Toxic vapors could be evolved from the combustion of the material.

Section V - Health Hazard Data

Effects of Overexposure: Chronic exposure to organic solvent has been associated with various neurotoxic effects including brain damage. Nervous system damage or death. Prolonged vapor contact may cause conjunctivitis; chronic inhalation may also include loss of memory, loss of intellectual ability, and loss of coordination. Corneal damage is possible but usually reversible. Repeated exposure to solvents can cause anemia, liver abnormalities, kidney damage or cardiac abnormalities.

Inhalation: Solvent vapors are irritating to the eyes, nose, and throat and respiratory tract resulting in dryness of the throat and tightness in the chest. Other symptoms include headache, nausea, narcosis, fatigue and loss of appetite.

Skin: May cause irritation or allergic skin response. May cause defatting, dryness, cracking, rash, redness or dermatitis.

Eyes: May cause corneal damage if left untreated which is slow to heal but usually reversible.

Skin Absorption Health Risks and Symptoms of Exposure: Solvents can penetrate the skin causing effects similar to those for acute inhalation symptoms.

Ingestion: Can cause irritation to the digestive tract including sore throat, abdominal pain, nausea, vomiting and diarrhea. Vomiting may cause aspiration of solvents resulting in chemical pneumonitis.

Carcinogenicity:

NTP: No IRAC Monographs: No OSHA Regulated: No

No listed ingredients of this product are regulated as carcinogens.

Medical Conditions Aggravated by Exposure: Respiratory Conditions or Other Allergic Responses.

Emergency First Aid Procedures:

Eyes: Flush eyes with water for at least fifteen minutes and consult a physician.

Skin: Wash affected area with soap and water and remove contaminated clothing promptly.

Inhalation: Remove victim to fresh air area and administer oxygen if necessary. Obtain medical attention.

Ingestion: Do not induce vomiting, never give anything by mouth to an unconscious person. Consult a physician.

Section VI - Reactivity Data

Stability: stable

Conditions To Avoid: Avoid excessive heat or open flames. This material should not be mixed with phosphorous containing material or oxidizers..

Incompatibility: Can react vigorously with strong oxidizing agents and phosphorous containing materials

Hazardous Decomposition Or Byproducts: carbon monoxide and dioxide.

Hazardous Polymerization: Will not occur..

Section VII - Spill Or Leak Procedures

Steps to be taken in case material is released or spilled:

Remove all sources of ignition and ventilate the area, wear appropriate protective equipment such as vapor cartridge or supplied air as necessary. Dike and absorb the material with absorbent such as clay and place in disposal containers.

Waste Disposal Method:

Dispose of the material in a waste disposal site in accordance with federal, state and local regulations. Empty containers should be handled with care due to product residue and possible vapor from organic solvents. Never use a gas or electric torch to cut the drum.

Section VIII - Special Protection Information

Respiratory Protection (Type): Use a NIOSH approved respirator as required to prevent overexposure to vapor in accordance with 29 CFR 1910.134. Use a positive pressure respirator when airborne concentrations are not known or if exceeding TLV’S or if working in a confined space. Always consider the hazards from all components in the mixed material state.

Ventilation: Exhaust ventilation sufficient to keep the airborne concentrations of the solvents and other hazardous materials below the toxic level concentrations.

Protective Gloves: Impervious gloves-neoprene or rubber.

Eye Protection: Splash goggles or glasses with side shield. If the environment warrants, a full face shield should be employed.

Other Protective Equipment: Wear body covering clothing and other coverings as necessary such as apron and appropriate footwear to avoid contact with material.

Section IX - Special Precautions

Precautions to be taken in handling and storing: Store in cool dry place; seal all partially used containers; wash with soap and water before eating, drinking, smoking or using toilet facilities; mixed materials contain the hazards of all the components therefore, read the MSDS’S of all the components prior to using material; properly label all containers.

Other Precautions: Avoid all skin contact; avoid breathing vapors generated from the material; observe conditions of good general hygiene and safe working practices; contaminated leather articles cannot be cleaned and must be discarded if contaminated with this product; wash all contaminated clothing prior to the reuse thereof; supply appropriate ventilation or engineering controls prior to using this product.

Part B

U.S. Department Of Labor

Occupational Safety And Health Administration

MATERIEL SAFETY DATA SHEET

Required Under USDL Safety And Health Regulations

(29 CFP 1910.1200 "Hazards Communication Standard")

Section I

Manufactured For: Gabriel First Corp.

Emergency Telephone: 1-800-424-9300

Address: 233 W Commercial Street East Rochester, NY 14445

Trade Name & Synonyms: ELITE CRU (PART B)

Chemical Family: Poly isocyanate adduct

Prepared On: 04/30/01

HIMS Codes:

HEALTH FLAMMABILITY REACITIVITY MPP

2 3 1 G

Section II - Product And Component Data

Component(s)/Chemical Names CAS PEL TVL STEL MM HG @ TEMP

Homopolymer of HDI 28182-81-2 1mg/m3 None None N/A

*Xylene 1330-20-7 100 ppm 100 ppm 150 ppm 5.1 @ 68 F

N-Butyl Acetate 123-86-4 150 ppm 150 ppm 200 ppm 10.0 @ 66 F

Indicates toxic chemical(s) subject to the reporting requirements of Section 313 of Title III and of $) CFR 372. Xylene Acgih STEL = 150 ppm. For HDI: Oral LD50> 10,000 mg/kg(Rats), Inhalation LC50 ranges from 137 to 1150 mg/m3, Eye irritation score 54.6/110 for a 24 hour exposure, Skin exposure - moderate irritate irritation score: 3.4/8 (rabbit).

Xylene: Weight Percent; 13

Section III - Physical Data

Boiling Point: 279 F

Specific Gravity (H₂O=1): 1.1

Vapor Pressure: N/A

Percent, Volatile By Volume(%):

Vapor Density(Air=1):N/A

Evaporation Rate: N/A

Solubility In Water: Negligible

Appearance And Odor: Pale yellow liquid with solvent odor.

Section IV - Fire And Explosion Hazard Data

Flash Point/Method used: 91 F (SETA Flash CC)

Flammable Limits: N/A

Extinguishing Media: Foam, Alcohol Foam, CO2, Dry Chemical

Unusual Fire and Explosion Hazards: If fire occurs, solvents may produce excessive pressure, sealed drums may rupture and ignite. Vapors are heavier than air and may travel along the ground and ignite by any source of ignition. During a fire, HDI vapors and other toxic gasses may be evolved. Containers may burst if contaminated with water. Vapor flashback to source is possible.

Section V - Health Hazard Data

Effects of Overexposure: Can cause sensitization by exposure through contact or high concentrations of vapor, over exposure to the material can cause cardiac abnormalities. Overexposure can possibly cause anemia, liver abnormalities, kidney damage, or eye damage. May cause asthma or other respiratory disorders, bronchitis, emphysema, hyperactivity and excema.

Inhalation: Can cause respiratory irritation, dizziness weakness, fatigue, nausea, headache and possible unconsciousness, burning sensation to mucous membranes, shortness of breath and flu like symptoms may occur.

Skin and Eye Exposure:

Skin: May cause irritation and dermatitis.

Eyes: May cause severe irritation, swelling, redness, tearing or blurred vision as well as corneal opacity and conjunctivitis.

Skin Absorption: Can cause reddening, swelling, rash, scaling or blistering. Overexposure may cause sensitization resulting in reaction to contact of small amounts.

Ingestion: Can cause gastrointestinal irritation, nausea, diarrhea, and vomiting. Aspiration of material into the lungs can cause chemical pneumonitis which can be fatal. Product can cause corrosive action to mucous membranes and digestive tracts.

Carcinogenicity:

NTP: No IRAC Monographs: No OSHA Regulated: No

No listed ingredients of this product are regulated as carcinogens.

Medical Conditions Aggravated by Exposure: Respiratory Conditions or Other Allergic Responses.

Emergency First Aid Procedures:

Eyes: Flush eyes with water for at least fifteen minutes and consult a physician.

Skin: Wash affected area with soap and water and remove contaminated clothing promptly.

Inhalation: Remove victim to fresh air area and administer oxygen if necessary. Obtain medical attention.

Ingestion: Do not induce vomiting, never give anything by mouth to an unconscious person. Consult a physician.

Section VI - Reactivity Data

Stability: stable

Conditions To Avoid: Avoid excessive heat or open flames as well as all sources of ignition such as sparks, heaters, static discharge, etc.

Incompatibility: Avoid water, amines, strong bases, alcohols, metal compounds, and surface active compounds.

Hazardous Decomposition Or Byproducts: May form toxic chemicals, carbon dioxide, carbon monoxide, oxides of nitrogen, HCN and HDI.

Hazardous Polymerization: May occur. Moisture or materials that react with isocyanates and temperatures above 400 F may cause polymerization.

Section VII - Spill Or Leak Procedures

Steps to be taken in case material is released or spilled: Wear respirator and protective clothing. Remove all source of ignitions. Remove excess with spark proof equipment and the remainder with an absorbent such as clay and place in disposal containers. Contained air respirator may be necessary.

Waste Disposal Method: Dispose of material in a waste disposal site in accordance with local, state and federal laws.

Section VIII - Special Protection Information

Respiratory Protection(Type): Use a NIOSH approved respirator as required to prevent overexposure to vapor in accordance with 29 CFR 1910.134. Use a positive pressure respirator when airborne concentrations are not known or if exceeding TLV’S or if working in a confined space. Always consider the hazards from all components in the mixed material state.

Ventilation: Exhaust ventilation sufficient to keep the airborne concentrations of the solvents and other hazardous materials below the toxic level concentrations.

Protective Gloves: Impervious gloves-neoprene or rubber.

Eye Protection: Splash goggles or glasses with side shield. If the environment warrants, a full face shield should be employed.

Other Protective Equipment: Wear body covering clothing and other coverings as necessary such as apron and appropriate footwear to avoid contact with material.

Work/Hygienic Practices: Observe good general hygienic practices

Section IX - Special Precautions

Supplier Notification Under Section 313 of SARA

Pursuant to Title III of the Superfund Amendments and Reauthorization Act of 1986(SARA) and 40 CFR Part 372, our Product: ELITE CRU -Part B contains toxic chemicals in quantities subject to the reporting requirements under Section 313(See below).Effective January 1, 1989, any person who sells or otherwise distributes a mixture or trade name product containing toxic chemicals must provide written notice to the recipient with the first shipment in each calendar year. If the recipient repackages or otherwise redistributes this product a notice indicating that this product is subject to the reporting requirements of Section 313, including the reporting chemical name/category, CAS number and percent by weight, must accompany the shipment. Please note that the notification letter must be attached and remain attached to the Material Safety Data Sheet.

Contains: CAS Number Percent by Weight

Xylene 1330-20-7 13

This information is given in good faith, but no warranty expressed or implied is made. Our company believes that it is accurate to the best of it’s knowledge and relates only to the specific material designated herein.